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The two are often sold together as the "algae twins", but they do not even belong to the same kingdom: chlorella is a eukaryotic green alga, and spirulina is a cyanobacterium. Chlorella has a higher share of genuine B12 and far more chlorophyll. What they truly share is superfood marketing and uneven product quality: in one analysis, microcystin toxins were found in algae supplements only when they contained another cyanobacterium, AFA.
Chlorella is often sold to vegans as a source of B12. Testing shows that the cobalamin in most chlorella tablets is mainly genuine B12, but the amount varies enormously between products, from almost none to a great deal, and some also contain inactive look-alikes. So it cannot replace a B12 supplement: people eating mostly plants are safer with a B12 supplement that states its dose, or with fortified foods.